August 25, 2025

Un Number for Hazardous Materials: Your Essential Guide

Learn everything about UN number for hazardous materials—how to find, classify, and handle these codes for safe, compliant shipping.

Un Number for Hazardous Materials: Your Essential Guide

When you're dealing with hazardous materials, a UN number is the most important piece of information you'll work with. It's a simple four-digit code that serves as a universal ID for a specific dangerous substance, instantly telling everyone from warehouse workers to first responders what they're up against. Think of it as a safety language that everyone, everywhere, understands.

What Are UN Numbers and Why Do They Matter?

Imagine a UN number as a chemical's passport. Just like your passport identifies you and your country of origin, a UN number instantly identifies a hazardous material and the specific dangers it poses. This isn't just about following rules; it's the very foundation of safe hazmat shipping.

This system is a core part of the Globally Harmonized System (GHS), which was created to get everyone on the same page. No matter if your cargo is on a truck, train, ship, or plane, that little four-digit number cuts through any confusion.

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The Global Standard for Safety

The whole UN numbering system came from a massive international push to standardize how we transport dangerous goods. After the 1992 Earth Summit, the United Nations put this system in place to assign a unique four-digit code to hazardous substances, making them recognizable across the globe.

Today, with over 3,600 UN numbers and counting, the system covers a huge range of materials, from common flammables to rare toxic gases. It's a simple, effective shorthand that makes international trade dramatically safer.

Getting this number right is the first and most critical step in avoiding expensive mistakes or, worse, dangerous accidents. That single number determines everything else:

  • Proper Packaging: What kind of drum, box, or tank is needed to contain the material securely.
  • Labeling and Placarding: Which specific warning labels and placards must be slapped on the package and vehicle.
  • Handling Procedures: The exact steps for loading, securing, and moving the shipment.

A shipment of UN1203 (Gasoline) is handled with the same care and procedures in Houston as it is in Hamburg. By standardizing this communication, UN numbers remove guesswork and protect everyone in the supply chain.

Key Hazmat Identifiers at a Glance

When you look at a shipping paper or a hazmat placard, you'll see a few key identifiers working together. This table breaks down the core components, giving you a quick reference for your shipping documents.

IdentifierWhat It Tells YouExample
UN NumberThe specific ID for the substance. This is the most crucial piece of info.UN1203 (Gasoline)
Proper Shipping NameThe standardized name of the material, which must be used on all documents.Gasoline
Hazard ClassA number from 1 to 9 indicating the primary type of danger (e.g., flammable, corrosive).Class 3 (Flammable Liquid)
Packing GroupA Roman numeral (I, II, or III) indicating the degree of danger. I is high, II is medium, and III is low.PG II (Medium Danger)

This combination of information gives anyone who encounters your shipment a complete, at-a-glance picture of what's inside and how to handle it safely. It's a system designed for clarity and immediate understanding.

How to Find the Right UN Number for Your Shipment

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So, how do you track down the correct UN number for what you’re shipping? It’s actually a lot simpler than it sounds. Your number one resource is the product's Safety Data Sheet, or SDS.

Think of the SDS as the material’s official biography. The manufacturer is required to provide it, and it tells you everything you need to know about the substance—including exactly how to ship it safely.

When you get your hands on the SDS, your destination is Section 14: Transport Information. This part is written specifically for logistics and contains all the crucial details you need to get your shipment on the road.

Your Guide to the Safety Data Sheet (SDS)

The SDS is standardized, so the information is always in the same place. Just head straight to Section 14 to find what you’re looking for.

Here’s a quick look at the critical info you’ll find there:

  • UN Number: The four-digit code we've been talking about.
  • Proper Shipping Name (PSN): This is the official name that must appear on all your documents.
  • Transport Hazard Class: Tells you the primary danger (e.g., Flammable, Corrosive, etc.).
  • Packing Group (PG): Roman numerals (I, II, or III) that signal how dangerous the material is.

This section is your cheat sheet for compliant shipping. It takes all the guesswork out of the process and gives you the exact data needed for your paperwork and labels.

What If You Don't Have an SDS?

While the SDS should always be your first stop, what happens if you can't find it? Don't panic; you have other options.

Government bodies like the Pipeline and Hazardous Materials Safety Administration (PHMSA) offer online databases. You can search their Hazardous Materials Table to look up your substance. It’s a great backup resource.

However, the responsibility for correct classification ultimately falls on you, the shipper. That’s why you should always try to get the official SDS from the manufacturer first. Getting the classification right is a cornerstone of learning how to ship freight safely and legally.

Key Takeaway: The Safety Data Sheet (SDS) is your best friend when shipping hazardous materials. Always check Section 14 first to find the correct UN number and ensure your shipment is properly identified and documented before it goes anywhere.

Decoding the 9 Hazard Classes

Every single UN number for hazardous materials is tied directly to one of nine hazard classes. These aren't just random buckets; they're the essential playbook telling you exactly how your LTL or FTL freight needs to be packaged, labeled, and moved to keep everyone safe.

Think of it like genres in a bookstore. You wouldn't treat a fragile, antique book the same way you'd toss a paperback into your bag, right? Similarly, you can't handle flammable liquids (Class 3) the same way you’d handle corrosive materials (Class 8). Each class comes with its own specific risks and safety rules.

For instance, a shipment of paint thinner (UN1263, Class 3) demands proper ventilation and must be kept far from anything that could spark a fire. On the other hand, industrial cleaners (UN1760, Class 8) need special packaging that won’t get eaten away by the chemicals. When you understand the "why" behind these rules, compliance stops being a chore and becomes a smart part of your safety plan.

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The Structure Behind the System

So who makes all these rules? The United Nations has a Subcommittee of Experts that manages this whole system, from assigning the numbers to defining what goes into each hazard class.

This infographic breaks down how the classification and numbering work hand-in-hand.

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The real beauty of this structure is its simplicity. Every UN number points to a specific hazard class, creating an unmistakable link between a substance’s identity and its dangers. No guesswork involved.

This universal language is the foundation of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS), a major UN initiative from 2003. Before the GHS, shippers were stuck navigating a chaotic mess of national regulations. Now, with the UN number system at its core, the GHS gives us a consistent, worldwide way to talk about chemical safety.

The impact has been huge. By 2017, nearly 90% of participating countries were on board with these standards, showing just how badly a single, clear system was needed.

Common UN Numbers You'll See Out in the Wild

Once you know what to look for, you'll start noticing the same UN numbers again and again on shipping paperwork. It’s one thing to read the regulations, but it’s another to see the codes on the actual drums and pallets moving through your warehouse.

Think about it—some materials are just incredibly common across industries. You'll constantly see UN1203 for gasoline, a staple for fuel distributors. Another big one is UN1830, which is sulfuric acid, a workhorse chemical used in everything from car batteries to manufacturing.

Recognizing these common codes helps you build that real-world, practical familiarity with hazmat shipping.

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What Does 'N.O.S.' Mean?

So, what happens when you’re shipping something that doesn't have its own specific UN number? This is where a little abbreviation, n.o.s., comes into play. It simply means "Not Otherwise Specified."

These n.o.s. entries are essentially catch-all categories for groups of similar chemicals. For example, UN1993 is one of the most common UN numbers out there. It covers Flammable Liquid, n.o.s., a broad category that could include anything from certain paint thinners to specialized industrial solvents.

The key thing to remember is that if you use an n.o.s. entry, you also have to list the technical names of the hazardous ingredients in parentheses right on the shipping documents.

The Bottom Line: A specific number like UN1203 for gasoline is cut-and-dry. But for mixtures or unique substances, n.o.s. numbers like UN1993 give us a way to classify them properly so everyone handling the shipment knows what they're dealing with.

Here are a few other common examples you're likely to run into:

  • UN1760: Corrosive Liquid, n.o.s. (often used for industrial cleaning compounds)
  • UN1075: Petroleum Gases, Liquefied (this is your propane or butane)
  • UN3082: Environmentally Hazardous Substance, Liquid, n.o.s.

Getting a handle on these common codes and the n.o.s. designation will make you feel a lot more confident when you're looking over hazmat paperwork and getting your shipments ready to go.

The High Cost of Using the Wrong UN Number

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It might seem like a simple typo, but getting the UN number for hazardous materials wrong can have massive consequences. This isn't just about getting the paperwork right—it's about real-world safety and protecting your business from major financial hits.

A wrong number creates serious safety hazards. Imagine first responders arriving at an accident with the wrong information. Their entire emergency plan could be dangerously flawed, leading to improper containment or even life-threatening chemical reactions. It puts everyone—drivers, emergency crews, and the public—at serious risk.

On top of the immediate danger, the business impact is severe. An incorrect UN number can trigger a chain reaction of costly disruptions and steep regulatory penalties.

Financial and Reputational Risks

The fallout from a single incorrect UN number can ripple through your entire operation, hitting your budget and your brand where it hurts.

  • Steep Fines: Regulatory bodies like the Department of Transportation (DOT) don't take these errors lightly. Fines for non-compliance can easily run into thousands of dollars per violation.
  • Shipment Delays and Rejections: Carriers will stop a shipment dead in its tracks if the documentation is wrong. That means frustrating delays, rejected loads, and unhappy customers wondering where their delivery is.
  • Damaged Reputation: Making these kinds of mistakes consistently tells your partners and customers that you don't have your act together. It erodes trust and can send them looking for a more reliable shipper.

Mistakes aren't just costly; they're a liability. Effective transportation risk management starts with getting every detail right, ensuring your shipments are safe, compliant, and dependable from start to finish.

Don't let a preventable error throw your FTL or LTL supply chain into chaos. We can connect you with certified hazmat carriers who know how to get it right, every time.

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Frequently Asked Questions About UN Numbers

When you're dealing with hazardous materials, a few questions always seem to pop up. Let's tackle some of the most common ones we hear from shippers to help keep your freight moving smoothly and safely.

What's the Difference Between a UN and an NA Number?

You might notice an "NA" number on some paperwork and wonder how it relates to a "UN" number. Think of it like a passport versus a driver's license.

A UN (United Nations) number is the global standard, your shipment's passport for travel by road, rail, air, or sea anywhere in the world. An NA (North American) number is like a domestic ID—it's only valid for ground shipments within the United States and Canada. If your freight is crossing an ocean, it absolutely must have a UN number.

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What If I Can't Find an SDS?

Your first stop for finding the correct UN number for hazardous materials should always be the Safety Data Sheet (SDS) from the manufacturer. It’s the definitive source.

But what if you truly can't get your hands on one? The next best place to look is the official Hazardous Materials Table. In the U.S., you can find this resource from the Pipeline and Hazardous Materials Safety Administration (PHMSA). While it's a solid backup, never forget that the shipper is ultimately responsible for classifying the material correctly.

Remember, as the shipper, the liability for proper classification falls squarely on your shoulders. Getting it wrong can lead to costly fines and rejected shipments. Proper documentation is crucial, and so is having the right coverage. You can learn more in your guide to marine and cargo insurance.

Do All Hazardous Materials Have a UN Number?

Pretty much. The system is designed to cover nearly every substance considered hazardous for transport. It’s incredibly comprehensive.

However, there are a few exceptions. Some consumer goods that pose a very low risk might qualify for special provisions like "Limited Quantity" exemptions. These shipments often have different labeling requirements but still demand close attention to the regulations. Always check the specific rules for your product to stay compliant.


At FreightQuotesNow, we connect you with certified carriers who know the ins and outs of hazmat shipping. Get your free, no-obligation FTL or LTL quote today and ship with confidence.

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